祝艳
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电子邮箱: zhuyan@nju.edu.cn
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个人简介

伟德源自英国始于1946教授、博士生导师。主要从事催化科学和团簇化学研究,在构筑原子精确催化剂、建立明确构效关系、精准调控催化反应过程等方面开展深入探索和系统研究,为新催化剂设计和新催化过程开发提供坚实的科学基础和新技术。Angew. Chem.Nature Commun.J. Am. Chem. Soc.、Acc. Chem. Res.、ACS Catal.CCS Chem.等国内外期刊上发表通讯作者论文100余篇获授权发明专利10余项。主编出版专著1部。获得国家杰出青年科学基金。入选江苏双创人才、六大人才高峰高层次人才、百人计划等。入选中国青年化学家元素周期表代言金元素。获得The Distinguished Lectureship Award of The Chemical Society of Japan、首届江苏青年女科学家。担任物理化学学报、Nano Research、燃料化学学报等青年编委,Green Energy & Environment、Current Opinion in Green and Sustainable Chemistry编委,Sustainable Chemistry for Climate Action编辑。担任中国化学会晶体化学专委会副主任以及绿色化学专委会、催化专委会、二氧化碳化学专委会委员。

欢迎对催化化学、团簇化学、能源材料化学等领域感兴趣的优秀员工加入课题组做本科毕业设计、攻读博士学位,诚聘博士后、特任研究员加盟课题组开展科研工作。

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工作经历
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研究方向

发展高性能催化体系,创制具有单一尺寸分布的催化剂,将每一个反应物分子高选择性转化为目标分子是精准催化追求的目标。金属团簇具有确定的原子数目和精确的结构,可准确确定活性位并建立原子尺度的构效关系,为深入理解催化作用机制提供了新的材料体系。金属团簇兼具均相催化剂的精确与多相催化剂的规模应用,即精准与高效,可称为连接均相-多相催化的桥梁。

本课题组聚焦于面向资源与能源分子高效转化的精准团簇催化体系研究,发展精准调控金属团簇结构和组成策略,把握团簇催化剂本征催化性能,深化对精准团簇催化体系的科学认识,开展基于金属团簇的催化技术研究,为反应分子的精准转化创造新催化材料,开拓高端化学品制造的新技术。

学术成果

Selected Publications

1. T.Song, C.Shen, Y.Tian, Q.Zhai, S.Tang, Y. Zhu. A Heterodimeric Cluster-based Pair Catalyst for Electrochemical Synthesis of Cyclohexanone Oxime. Angew. Chem. Int. Ed. 2025, 64, e202507569.

2. X.Liu, J.Tang, F.Zhao, M.Zhou, S.Ye, D.Hong, Y.Tian, Y.Zhao, F.Tian, T.Song, X.Cai, Y.Tian, W.Zhang, Q.Li, Y.Zhu. Atomically Engineered Trimetallic Nanoclusters Towards Enhanced Photoluminescence and Photoinitiation Activity. Adv. Mater. 2025, 37, 2417984. 

3. T.Sun, B.Ge, S.Huang, X.Wang, Y.Tian, X.Cai, W.Ding, Y.Zhu. Heterogeneous Catalysis of Molecular-Like Au8M(PPh3)8n+ Clusters Cultivated in Mesoporous SBA-15. Angew. Chem. Int. Ed. 2024, 63, e202420274.

4. X.Cai, Y.Tian, H.Wang, S.Huang, X.Liu, G.Li, W.Ding, Y.Zhu. Catalytic N-Formylation of CO2 by Atomically Precise Au8Pd1(DPPF)42+ Clusters into a Two-Dimensional Metal-Organic Framework. Angew. Chem. Int. Ed. 2024, 63, e202414030.

5. G.Li, J.Hou, X.Lei, D.Li, E.Yu, W.Hu, X.Cai, X.Liu, M.Chen, Y.Zhu. Reactivity and Recyclability of Ligand-Protected Metal Cluster Catalysts for CO2 Transformation. Angew. Chem. Int. Ed. 2023, 62, e202216735.

6. X.Liu, X.Cai, Y.Zhu. Catalysis Synergism by Atomically Precise Bimetallic Nanoclusters Doped with Heteroatoms. Acc. Chem. Res. 2023, 56, 1528.

7. X.Cai, Y.Liu, G.Li, W.Hu, X.Liu, M.Chen, W.Ding, Y.Zhu. The functionalized heterogeneous catalyst from atomically precise Pd1Au8 cluster facilitates the carbon-carbon bond construction. Adv. Mater. 2023, 35, 2301466.

8. T.Song, Z.Yao, G.Li, X.Cai, X.Liu, Y.Wang, W.Ding, Y.Zhu. Catalytic Activity Coupled with Structural Stability within a Heterodimeric Au29(SR)19 Cluster. ACS Catal. 2023, 13, 10878.

9. Q.Yuan, S.Huang, H.Lin, G.Saranya, W.Hu, G.Li, X.Cai, X.Liu, M.Chen, W.Ding, Y.Zhu. Atomically Precise AgCu Clusters Affixed to SiO2 Aerogel for N-formylation of Amines. ACS Catal. 2023, 13, 16188.

10. X.Liu, E.Wang, M.Zhou, Y.Wan, Y.Zhang, H.Liu, Y.Zhao, J.Li, Y.Gao, Y.Zhu. Asymmetrically Doping a Platium Atom into a Au38 Nanocluster for Changing the Electron Configuration and Reactivity in Electrocatalysis. Angew. Chem. Int. Ed. 2022, 61, e202207685.

11. G.Li, X.Sui, X.Cai, W.Hu, X.Liu, M.Chen, Y.Zhu. Precisely Constructed Silver Active Sites in Gold Nanoclusters for Chemical Fixation of CO2. Angew. Chem. Int. Ed. 2021, 60, 10573.

12. Y.Sun, X.Liu, K.Xiao, Y.Zhu, M.Chen. Active-Site Tailoring of Gold Cluster Catalysts for Electrochemical CO2 Reduction. ACS Catal. 2021, 11, 11551.

13. X.Liu, W.Xu, X.Huang, E.Wang, X.Cai, Y.Zhao, J.Li, M.Xiao, C.Zhang, Y.Gao, W.Ding, Y.Zhu. De novo design of Au36(SR)24 nanoclusters. Nature Commun. 2020, 11, 3349.

14. X.Cai, W.Hu, S.Xu, D.Yang, M.Chen, M.Shu, R.Si, W.Ding, Y.Zhu. Structural Relaxation Enabled by Internal Vacancy Available in a 24-atom Gold Cluster Reinforces Catalytic Reactivity. J. Am. Chem. Soc. 2020, 142, 4141.

15. G.Li, W.Hu, Y.Sun, J.Xu, X.Cai, X.Cheng, Y.Zhang, A.Tang, X.Liu, M.Chen, W.Ding, Y.Zhu. Reactivity and Lability of Modulated by a Valence Electron Moving in and out of 25-Atom Gold Nanoclusters. Angew. Chem. Int. Ed. 2020, 59, 21135.

16. D.Yang, W.Pei, S.Zhou, J.Zhao, W.Ding, Y.Zhu. Controllable Conversion of CO2 on Non-metallic Gold Clusters. Angew. Chem. Int. Ed. 2020, 59, 1919.

17. X.Liu, G.Saranya, X.Huang, X.Cheng, R.Wang, M.Chen, C.Zhang, T.Li, Y.Zhu. Ag2Au50(PET)36 Nanocluster: Dimeric Assembly of Au25(PET)18 Enabled by Silver Atoms. Angew. Chem. Int. Ed. 2020, 59, 13941.

18. X.Cai, G.Saranya, K.Shen, M.Chen, R.Si, W.Ding, Y.Zhu. Reversible Switching of Catalytic Activity by Shuttling an Atom into and out of Au Nanoclusters. Angew. Chem. Int. Ed. 2019, 58, 9964.

19. Y.Liu, X.Chai, X.Cai, M.Chen, R.Jin, W.Ding, Y.Zhu. Central Doping of a Foreign Atom into the Silver Cluster for Catalytic Conversion of CO2 toward C-C Bond Formation. Angew. Chem. Int. Ed. 2018, 57, 9775.

20. Q.Li, J.C. Russell, T.Luo, X.Roy, N.L. Rosi, Y.Zhu, R.Jin. Modulating the Hierarchical Fibrous Assembly of Au Nanoparticles with Atomic Precision. Nature Commun. 2018, 9, 3871.

课程名称、上课时间地点

大学化学

工业催化理论与应用

教学大纲、考试要求
教学资源(上课讲义、参考资料等)

大学化学,傅献彩等编著,高等教育出版社

物理化学,傅献彩等编著,高等教育出版社


课题组风采

我们是朝气蓬勃努力向上的Cluster课题组