题 目:Molecular Behavior in Small Spaces Abstract : This lecture follows the course of molecular recognition by synthetic receptors that completely surround their targets: encapsulation complexes. These operate through the proper filling of space and reveal new forms of stereochemistry, isomerism, asymmetry, contortions and reactivity of molecules held inside. Capsules with spacers offer a set of molecular devices that operate through compression and expansion of alkanes. An encapsulation complex of anandamide is shown below. 欢迎参加! 有机化学学科 |